| 1 | James Ruse Agricultural High School (Public) | Carlingford | 736 |
| 2 | North Sydney Girls High School (Public) | Crows Nest | 725 |
| 3 | North Sydney Boys High School (Public) | Crows Nest | 718 |
| 4 | Sydney Girls High School (Public) | Surry Hills | 717 |
| 5 | Sydney Boys High School (Public) | Surry Hills | 707 |
| 6 | Hornsby Girls High School (Public) | Hornsby | 705 |
| 6 | Fort Street High School (Public) | Petersham | 705 |
| 8 | St George Girls High School (Public) | Kogarah | 704 |
| 9 | Sydney Grammar School (Private) | Darlinghurst | 703 |
| 10 | Normanhurst Boys High School (Public) | Normanhurst | 702 |
| 11 | Baulkham Hills High School (Public) | Baulkham Hills | 701 |
| 12 | Northern Beaches Secondary College, Manly Selective Campus (Public) | North Curl Curl | 700 |
| 13 | Girraween High School (Public) | Girraween | 698 |
| 14 | Hurlstone Agricultural High School (Public) | Glenfield | 693 |
| 15 | Sydney Technical High School (Public) | Bexley | 689 |
| 16 | Conservatorium High School (Public) | Sydney | 686 |
| 17 | Merewether High School (Public) | Broadmeadow | 684 |
| 18 | Caringbah High School (Public) | Caringbah | 683 |
| 19 | Penrith High School (Public) | Penrith | 682 |
| 20 | Smith's Hill High School (Public) | Wollongong | 680 |
| 21 | Gosford High School (Public) | Gosford | 676 |
| 22 | St Aloysius College (Private) | Milsons Point | 672 |
| 23 | Abbotsleigh (Private) | Wahroonga | 664 |
| 24 | Ascham School (Private) | Edgecliff | 662 |
| 25 | SCEGGS Darlinghurst (Private) | Darlinghurst | 658 |
| 26 | Meriden School (Private) | Strathfield | 652 |
| 27 | Loreto Kirribilli (Private) | Kirribilli | 650 |
| 27 | Blessed Mary MacKillop College (Private) | Wagga Wagga | 650 |
| 29 | Pymble Ladies' College (Private) | Pymble | 649 |
| 29 | Queenwood School for Girls Ltd (Private) | Mosman | 649 |
| 31 | Ravenswood School for Girls (Private) | Gordon | 646 |
| 32 | Newcastle Grammar School (Private) | Newcastle | 645 |
| 33 | Sydney Church of England Grammar School (Private) | North Sydney | 642 |
| 33 | Sefton High School (Public) | Sefton | 642 |
| 33 | Loreto Normanhurst (Private) | Normanhurst | 642 |
| 36 | Tangara School for Girls (Private) | Cherrybrook | 641 |
| 36 | Cranbrook School (Private) | Bellevue Hill | 641 |
| 36 | Christadelphian Heritage College (Private) | Cooranbong | 641 |
| 39 | Wenona School (Private) | North Sydney | 640 |
| 39 | Malek Fahd Islamic School (Private) | Greenacre | 640 |
| 39 | Trinity Grammar School (Private) | Summer Hill | 640 |
| 42 | Tara Anglican School for Girls (Private) | North Parramatta | 639 |
| 42 | Presbyterian Ladies College Sydney (Private) | Croydon | 639 |
| 44 | The Scots College (Private) | Bellevue Hill | 638 |
| 45 | Arden Anglican School (Private) | Beecroft | 637 |
| 45 | Pittwater House Grammar School (Private) | Collaroy | 637 |
| 47 | Kincoppal - Rose Bay School of the Sacred Heart (Private) | Rose Bay | 636 |
| 47 | Roseville College (Private) | Roseville | 636 |
| 49 | Kambala (Private) | Rose Bay | 635 |
| 49 | Barker College (Private) | Hornsby | 635 |
