| 1 | James Ruse Agricultural High School (Public) | Carlingford | 711 |
| 2 | North Sydney Boys High School (Public) | Crows Nest | 686 |
| 3 | North Sydney Girls High School (Public) | Crows Nest | 682 |
| 4 | Baulkham Hills High School (Public) | Baulkham Hills | 681 |
| 5 | Hornsby Girls High School (Public) | Hornsby | 678 |
| 6 | Sydney Girls High School (Public) | Surry Hills | 677 |
| 7 | Sydney Boys High School (Public) | Surry Hills | 670 |
| 8 | Fort Street High School (Public) | Petersham | 665 |
| 9 | Sydney Grammar School (Private) | Darlinghurst | 664 |
| 10 | Girraween High School (Public) | Girraween | 663 |
| 11 | Normanhurst Boys High School (Public) | Normanhurst | 662 |
| 12 | St George Girls High School (Public) | Kogarah | 660 |
| 13 | Merewether High School (Public) | Broadmeadow | 656 |
| 14 | Northern Beaches Secondary College, Manly Selective Campus (Public) | North Curl Curl | 654 |
| 15 | Caringbah High School (Public) | Caringbah | 653 |
| 16 | Hurlstone Agricultural High School (Public) | Glenfield | 651 |
| 17 | Penrith High School (Public) | Penrith | 644 |
| 18 | Smith's Hill High School (Public) | Wollongong | 643 |
| 19 | Sydney Technical High School (Public) | Bexley | 642 |
| 20 | Gosford High School (Public) | Gosford | 640 |
| 21 | Abbotsleigh (Private) | Wahroonga | 627 |
| 22 | St Aloysius College (Private) | Milsons Point | 624 |
| 23 | Conservatorium High School (Public) | Sydney | 617 |
| 24 | SCEGGS Darlinghurst (Private) | Darlinghurst | 612 |
| 25 | Wenona School (Private) | North Sydney | 611 |
| 26 | Queenwood School for Girls Ltd (Private) | Mosman | 610 |
| 27 | Ascham School (Private) | Edgecliff | 609 |
| 28 | Kambala (Private) | Rose Bay | 608 |
| 29 | Kincoppal - Rose Bay School of the Sacred Heart (Private) | Rose Bay | 607 |
| 29 | Westmead Christian Grammar School (Private) | Westmead | 607 |
| 31 | Yeshiva College (Private) | Bondi | 606 |
| 32 | Meriden School (Private) | Strathfield | 605 |
| 32 | Presbyterian Ladies College Sydney (Private) | Croydon | 605 |
| 34 | MLC School (Private) | Burwood | 604 |
| 34 | Pymble Ladies' College (Private) | Pymble | 604 |
| 36 | Barker College (Private) | Hornsby | 603 |
| 36 | Sydney Distance Education High School (Public) | Woolloomooloo | 603 |
| 38 | Tara Anglican School for Girls (Private) | North Parramatta | 602 |
| 39 | Ravenswood School for Girls (Private) | Gordon | 601 |
| 40 | Tangara School for Girls (Private) | Cherrybrook | 600 |
| 40 | Redeemer Baptist School (Private) | North Parramatta | 600 |
| 42 | The King's School (Private) | North Parramatta | 596 |
| 42 | Reddam House (Private) | North Bondi | 596 |
| 42 | Cranbrook School (Private) | Bellevue Hill | 596 |
| 45 | Arden Anglican School (Private) | Beecroft | 594 |
| 46 | Sydney Church of England Grammar School (Private) | North Sydney | 593 |
| 46 | Newington College (Private) | Stanmore | 593 |
| 48 | Roseville College (Private) | Roseville | 592 |
| 48 | Hunter Valley Grammar School (Private) | Ashtonfield | 592 |
| 48 | Killara High School (Public) | Killara | 592 |
